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Asymmetric total synthesis of ent-cyclooroidin
[Image: see text] An enantiospecific total synthesis of the pyrrole-imidazole natural product cyclooroidin from histidine is described. The key N1-C9 bond is constructed through an intramolecular SN2-type of reaction of a chloro ester. Subsequent imidazole C2-azidation at the 2-position, pyrrole bro...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3099645/ https://ncbi.nlm.nih.gov/pubmed/20929213 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol1020916 |
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