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Pd-Catalyzed Aerobic Oxidative Coupling of Arenes: Evidence for Transmetalation between Two Pd(II)-Aryl Intermediates

[Image: see text] Pd-catalyzed aerobic oxidative coupling of arenes provides efficient access to biaryl compounds. The biaryl product forms via C–H activation of two arenes to afford a Pd(II)ArAr′ intermediate, which then undergoes C–C reductive elimination. The key Pd(II)ArAr′ intermediate could fo...

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Autors principals: Wang, Dian, Izawa, Yusuke, Stahl, Shannon S.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2014
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4161672/
https://ncbi.nlm.nih.gov/pubmed/24965384
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja505405u
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