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Kinetic and Spectroscopic Studies of Aerobic Copper(II)-Catalyzed Methoxylation of Arylboronic Esters and Insights into Aryl Transmetalation to Copper(II)
We previously reported a preliminary mechanistic study of aerobic Cu(OAc)(2)-catalyzed methoxylation of 4-tolylboronic ester (King, et al. J. Am. Chem. Soc., 2009, 131, 5044–5045), which revealed that aryl transmetalation from the boronic ester to Cu(II) is the turnover-limiting step. In the present...
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| Hlavní autoři: | , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2012
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3509420/ https://ncbi.nlm.nih.gov/pubmed/23204631 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om300586p |
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