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A New Reactivity Mode of Diazo-Group: Diastereoselective 1,3-Aminoalkylation Reaction of β-Amino-α-Diazoesters Towards Triazolines()
A novel reactivity mode of a diazo-group, the 1,3-addition of a nucleophile and an electrophile to the diazo-group, has been realized in the intramolecular aminoalkylation of β-amino-α-diazoesters to form tetrasubstituted 1,2,3-triazolines. The reaction proved to have a broad scope, good functional...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2014
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4157640/ https://ncbi.nlm.nih.gov/pubmed/24986811 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201404352 |
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