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Low-spin pseudotetrahedral Fe(I) sites in Fe(2)(μ-S) complexes
Fe(I) centers in iron-sulfide complexes have little precedent in synthetic chemistry despite a growing interest in the possible role of unusually low-valent iron in metalloenzymes that feature iron-sulfur clusters. A series of three diiron (L(3)Fe)(2)(μ-S) complexes that can be isolated and characte...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4155920/ https://ncbi.nlm.nih.gov/pubmed/24753364 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201401018 |
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