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Alkynes as Allylmetal Equivalents in Redox-Triggered C–C Couplings to Primary Alcohols: (Z)-Homoallylic Alcohols via Ruthenium-Catalyzed Propargyl C–H Oxidative Addition
[Image: see text] The cationic ruthenium catalyst generated upon the acid–base reaction of H(2)Ru(CO)(PPh(3))(3) and 2,4,6-(2-Pr)(3)PhSO(3)H promotes the redox-triggered C–C coupling of 2-alkynes and primary alcohols to form (Z)-homoallylic alcohols with good to complete control of olefin geometry....
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| Main Authors: | , , , , |
|---|---|
| Format: | Artigo |
| Language: | Inglês |
| Published: |
American Chemical
Society
2014
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| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4151781/ https://ncbi.nlm.nih.gov/pubmed/25075434 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja505962w |
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