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Concise Chemoenzymatic Three-Step Total Synthesis of Isosolenopsin through Medium Engineering
A short and efficient total synthesis of the alkaloid isosolenopsin and its enantiomer has been achieved. The key step was a ω-transaminase-catalysed regioselective monoamination of the diketone pentadecane-2,6-dione, which was obtained in a single step through the application of a Grignard reaction...
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| Glavni autori: | , , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
WILEY-VCH Verlag
2013
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4151137/ https://ncbi.nlm.nih.gov/pubmed/25191103 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201300157 |
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