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One-pot stereoselective synthesis of α,β-differentiated diamino esters via the sequence of aminochlorination, aziridination and intermolecular S(N)2 reaction

We report here an efficient one-pot method for the synthesis of α,β-differentiated diamino esters directly from cinnamate esters using N,N-dichloro-p-toluenesulfonamide and benzylamine as nitrogen sources. The key transformations include a Cu-catalyzed aminohalogenation and aziridination, followed b...

पूर्ण विवरण

में बचाया:
ग्रंथसूची विवरण
मुख्य लेखकों: Xiong, Yiwen, Qian, Ping, Cao, Chenhui, Mei, Haibo, Han, Jianlin, Li, Guigen, Pan, Yi
स्वरूप: Artigo
भाषा:Inglês
प्रकाशित: Beilstein-Institut 2014
विषय:
ऑनलाइन पहुंच:https://ncbi.nlm.nih.gov/pmc/articles/PMC4142878/
https://ncbi.nlm.nih.gov/pubmed/25161740
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.189
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