N,N-Diisopropyl-N-phosphonyl Imines Lead to Efficient Asymmetric Synthesis of Aziridine-2-Carboxylic Esters

Highly diastereoselective asymmetric synthesis of chiral aziridine-2-carboxylic esters is reported for 20 examples with good yields (51–87%) and excellent diastereoselectivities (>99:1 dr for most cases). The modified N-phosphonyl imines are proven to be superior to previous imine auxiliaries for...

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Main Authors: Kattamuri, Padmanabha V., Xiong, Yiwen, Pan, Yi, Li, Guigen
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3653188/
https://ncbi.nlm.nih.gov/pubmed/23563304
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3ob40251g
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