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Aqueous alkali halide solutions: can osmotic coefficients be explained on the basis of the ionic sizes alone?

We use the AMSA, associative mean spherical theory of associative fluids, to study ion–ion interactions in explicit water. We model water molecules as hard spheres with four off-center square-well sites and ions as charged hard spheres with sticky sites that bind to water molecules or other ions. We...

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Autori principali: Kalyuzhnyi, Yu V., Vlachy, Vojko, Dill, Ken A.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2010
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4142491/
https://ncbi.nlm.nih.gov/pubmed/20405084
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b924735a
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