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Aqueous alkali halide solutions: can osmotic coefficients be explained on the basis of the ionic sizes alone?

We use the AMSA, associative mean spherical theory of associative fluids, to study ion–ion interactions in explicit water. We model water molecules as hard spheres with four off-center square-well sites and ions as charged hard spheres with sticky sites that bind to water molecules or other ions. We...

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Detalhes bibliográficos
Main Authors: Kalyuzhnyi, Yu V., Vlachy, Vojko, Dill, Ken A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4142491/
https://ncbi.nlm.nih.gov/pubmed/20405084
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b924735a
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