Synthetic and Mechanistic Aspects of the Regioselective Base-Mediated Reaction of Perfluoroalkyl- and Perfluoroarylsilanes with Heterocyclic N-Oxides

The scope and mechanistic implications of the direct transformation of heterocyclic N-oxides to 2-trifluoromethyl-, and related perfluoroalkyl- and perfluoroaryl-substituted N-heterocycles has been studied. The reaction is effected by perfluoroalkyl- and perfluorophenyltrimethylsilane in the presenc...

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Bibliographic Details
Main Authors: Stephens, David E., Chavez, Gabriel, Valdes, Martin, Dovalina, Monica, Arman, Hadi D., Larionov, Oleg V.
Format: Artigo
Language:Inglês
Published: 2014
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4134925/
https://ncbi.nlm.nih.gov/pubmed/24993899
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4ob01088d
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