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Insights into the mechanistic and synthetic aspects of the Mo/P-catalyzed oxidation of N-heterocycles()

A Mo/P catalytic system for an efficient gram-scale oxidation of a variety of nitrogen heterocycles to N-oxides with hydrogen peroxide as terminal oxidant has been investigated. Combined spectroscopic and crystallographic studies point to the tetranuclear Mo(4)P peroxo complex as one of the active c...

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Detalhes bibliográficos
Main Authors: Larionov, Oleg V., Stephens, David, Mfuh, Adelphe M., Arman, Hadi D., Naumova, Anastasia S., Chavez, Gabriel, Skenderi, Behije
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4134924/
https://ncbi.nlm.nih.gov/pubmed/24643619
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4ob00115j
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