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Experimental and Mechanistic Analysis of the Palladium-Catalyzed Oxidative C8-Selective C–H Homocoupling of Quinoline N-Oxides

A novel site-selective palladium-catalyzed oxidative C8–H homocoupling reaction of quinoline N-oxides has been developed. The reaction affords substituted 8,8'-biquinolyl N,N'-dioxides that can be readily converted to a variety of functionalized 8,8'-biquinolyls. Mechanistic studies p...

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Détails bibliographiques
Publié dans:Chem Commun (Camb)
Auteurs principaux: Stephens, David E., Lakey-Beitia, Johant, Chavez, Gabriel, Ilie, Carla, Arman, Hadi D., Larionov, Oleg V.
Format: Artigo
Langue:Inglês
Publié: 2015
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4714569/
https://ncbi.nlm.nih.gov/pubmed/25966913
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cc02227d
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