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Iron Porphyrin Carbene Catalytic Intermediates: Structures, Mössbauer and NMR Spectroscopic Properties, and Bonding()

Iron porphyrin carbenes (IPCs) are thought to be intermediates involved in the metabolism of various xenobiotics by cytochrome P450, as well as in chemical reactions catalyzed by metalloporphyrins and engineered P450s. While early work proposed IPCs to contain Fe(II), more recent work invokes a doub...

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Autors principals: Khade, Rahul L., Fan, Wenchao, Ling, Yan, Yang, Liu, Oldfield, Eric, Zhang, Yong
Format: Artigo
Idioma:Inglês
Publicat: 2014
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4124075/
https://ncbi.nlm.nih.gov/pubmed/24910004
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201402472
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