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Iron Porphyrin Carbene Catalytic Intermediates: Structures, Mössbauer and NMR Spectroscopic Properties, and Bonding()
Iron porphyrin carbenes (IPCs) are thought to be intermediates involved in the metabolism of various xenobiotics by cytochrome P450, as well as in chemical reactions catalyzed by metalloporphyrins and engineered P450s. While early work proposed IPCs to contain Fe(II), more recent work invokes a doub...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4124075/ https://ncbi.nlm.nih.gov/pubmed/24910004 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201402472 |
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