Cooperativity in O2 binding to iron porphyrins.

The solid-gas O2 binding equilibrium has been studied for for ferrous "picket fence" porphyrinates with sterically hindered axial imidazoles. Such systems show significant cooperativity in their binding of O2: at low O2 pressures a low O2 affinity form exists, and at high O2 pressures a higher O2 af...

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Publié dans:	Proc Natl Acad Sci U S A
Auteurs principaux:	Collman, J P, Brauman, J I, Rose, E, Suslick, K S
Format:	Artigo
Langue:	Inglês
Publié:	National Academy of Sciences 1978
Sujets:	Research Article
Accès en ligne:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC411404/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/274696/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.75.3.1052
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