Cooperativity in O2 binding to iron porphyrins.

The solid-gas O2 binding equilibrium has been studied for for ferrous "picket fence" porphyrinates with sterically hindered axial imidazoles. Such systems show significant cooperativity in their binding of O2: at low O2 pressures a low O2 affinity form exists, and at high O2 pressures a hi...

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Bibliografiske detaljer
Main Authors: Collman, J P, Brauman, J I, Rose, E, Suslick, K S
Format: Artigo
Sprog:Inglês
Udgivet: 1978
Fag:
Research Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC411404/
https://ncbi.nlm.nih.gov/pubmed/274696
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