Model compounds for the T state of hemoglobin.

O2 binding to a series of ferrous and cobaltous "picket fence" porphyrins is reported. N-Methylimidazole and covalently attached imidazoles gives O2 binding to ferrous porphyrins with deltaH degrees =-16.2 kcal/mol (-67.7 kJ/mol) and deltaS degrees =-40 eu (standard state, 1 atmosphere O2)...

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Dades bibliogràfiques
Autors principals: Collman, J P, Brauman, J I, Doxsee, K M, Halbert, T R, Suslick, K S
Format: Artigo
Idioma:Inglês
Publicat: 1978
Matèries:
Research Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC411295/
https://ncbi.nlm.nih.gov/pubmed/273219
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