טוען...
Epoxidation of olefins by cytochrome P-450 model compounds: mechanism of oxygen atom transfer.
The mechanism of the Mn(III) porphyrin-catalyzed epoxidation of olefins by lithium hypochlorite is examined. The active oxidant is thought to be a high-valent manganese-oxo complex. It is shown that a relatively stable intermediate is reversibly formed upon interaction of the olefin and the oxo comp...
שמור ב:
| הוצא לאור ב: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
National Academy of Sciences
1984
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC345259/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/6587349/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.81.10.3245 |
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