載入...
Epoxidation of olefins by cytochrome P-450 model compounds: mechanism of oxygen atom transfer.
The mechanism of the Mn(III) porphyrin-catalyzed epoxidation of olefins by lithium hypochlorite is examined. The active oxidant is thought to be a high-valent manganese-oxo complex. It is shown that a relatively stable intermediate is reversibly formed upon interaction of the olefin and the oxo comp...
Na minha lista:
| Main Authors: | , , , , |
|---|---|
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
1984
|
| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC345259/ https://ncbi.nlm.nih.gov/pubmed/6587349 |
| 標簽: |
添加標簽
沒有標簽, 成為第一個標記此記錄!
|