Cooperativity in O2 binding to iron porphyrins.
The solid-gas O2 binding equilibrium has been studied for for ferrous "picket fence" porphyrinates with sterically hindered axial imidazoles. Such systems show significant cooperativity in their binding of O2: at low O2 pressures a low O2 affinity form exists, and at high O2 pressures a higher O2 af...
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| 發表在: | Proc Natl Acad Sci U S A |
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| Principais autores: | , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
National Academy of Sciences
1978
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC411404/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/274696/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.75.3.1052 |
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