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Evaluating N-benzylgalactonoamidines as putative transition state analogs for β-galactoside hydrolysis

Experimental evidence is provided for p-methylbenzyl-D-galactonoamidine to function as a true transition state analog for the enzymatic hydrolysis of aryl-β-D-galactopyranosides by β-galactosidase (A. oryzae). The compound exhibits inhibition constants in the low nanomolar concentration range (12–56...

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Bibliographische Detailangaben
Hauptverfasser: Fan, Qiu-Hua, Striegler, Susanne, Langston, Rebekah G., Barnett, James D.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2014
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4096895/
https://ncbi.nlm.nih.gov/pubmed/24668069
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4ob00153b
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