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Hydroxyl-Directed Stereoselective Diboration of Alkenes
[Image: see text] An alkoxide-catalyzed directed diboration of alkenyl alcohols is described. This reaction occurs in a stereoselective fashion and is demonstrated with cyclic and acyclic homoallylic and bishomoallylic alcohol substrates. After oxidation, the reaction generates 1,2-diols such that t...
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| Hlavní autoři: | , , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
American Chemical
Society
2014
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| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4091278/ https://ncbi.nlm.nih.gov/pubmed/24941137 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja504228p |
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