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Hydroxyl-Directed Cross-Coupling: A Scalable Synthesis of Debromohamigeran E and Other Targets of Interest
A hydroxyl functional group positioned β to a pinacol boronate can serve to direct palladium-catalyzed cross-coupling reactions, apparently through the agency of a transiently formed palladium alkoxide. This feature can be used to control the reaction site in multiply borylated substrates and can ac...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4896638/ https://ncbi.nlm.nih.gov/pubmed/26125083 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05477 |
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