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Hydroxyl-Directed Stereoselective Diboration of Alkenes

[Image: see text] An alkoxide-catalyzed directed diboration of alkenyl alcohols is described. This reaction occurs in a stereoselective fashion and is demonstrated with cyclic and acyclic homoallylic and bishomoallylic alcohol substrates. After oxidation, the reaction generates 1,2-diols such that t...

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Detalhes bibliográficos
Main Authors: Blaisdell, Thomas P., Caya, Thomas C., Zhang, Liang, Sanz-Marco, Amparo, Morken, James P.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4091278/
https://ncbi.nlm.nih.gov/pubmed/24941137
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja504228p
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