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Scope and Mechanism of the Pt-Catalyzed Enantioselective Diboration of Monosubstituted Alkenes

The Pt-catalyzed enantioselective diboration of terminal alkenes can be accomplished in an enantioselective fashion in the presence of chiral phosphonite ligands. Optimal procedures and the substrate scope of this transformation are fully investigated. Reaction progress kinetic analysis and natural...

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Detalhes bibliográficos
Main Authors: Coombs, John R., Haeffner, Fredrik, Kliman, Laura T., Morken, James P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3805123/
https://ncbi.nlm.nih.gov/pubmed/23862690
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4041016
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