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On the Carbohydrate/DBU Co-Catalyzed Alkene Diboration: Mechanistic Insight Provides Enhanced Catalytic Efficiency and Substrate Scope
A mechanistic investigation of the carbohydrate/DBU co-catalyzed enantioselective diboration of alkenes is presented. These studies provide an understanding of the origin of stereoselectivity and also reveal a strategy for enhancing reactivity and broadening the substrate scope.
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6313253/ https://ncbi.nlm.nih.gov/pubmed/29442502 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b12316 |
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