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Catalytic Enantioselective Synthesis of anti Vicinal Silylboronates by Conjunctive Cross Coupling
Chiral 1,2-bimetallic reagents are useful motifs in synthetic chemistry. Although syn-1,2-bimetallic compounds can be prepared by alkene dimetallation, anti-1,2-bimetallics are still rare. The stereospecific 1,2-metallate shift that occurs during conjunctive cross-coupling is shown to enable a pract...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7359638/ https://ncbi.nlm.nih.gov/pubmed/32078229 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202000937 |
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