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Catalytic Enantioselective Synthesis of anti Vicinal Silylboronates by Conjunctive Cross Coupling

Chiral 1,2-bimetallic reagents are useful motifs in synthetic chemistry. Although syn-1,2-bimetallic compounds can be prepared by alkene dimetallation, anti-1,2-bimetallics are still rare. The stereospecific 1,2-metallate shift that occurs during conjunctive cross-coupling is shown to enable a pract...

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Foilsithe in:Angew Chem Int Ed Engl
Main Authors: Meng, Yan, Kong, Ziyin, Morken, James P.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2020
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7359638/
https://ncbi.nlm.nih.gov/pubmed/32078229
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202000937
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