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Gold-Catalyzed Allylation of Aryl Boronic Acids: Accessing Cross-Coupling Reactivity with Gold

A sp(3) – sp(2) C-C cross-coupling reaction catalyzed by gold in the absence of a sacrificial oxidant is described. Vital to the success of this method is the implementation of a bimetallic catalyst bearing a bis(phosphino)amine ligand. A mechanistic hypothesis is presented, and observable transmeta...

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Bibliografiske detaljer
Main Authors: Levin, Mark D., Toste, F. Dean
Format: Artigo
Sprog:Inglês
Udgivet: 2014
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4076148/
https://ncbi.nlm.nih.gov/pubmed/24799132
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201402924
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