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Highly Enantioselective Hiyama Cross-Coupling via Rh-Catalyzed Allylic Arylation of Racemic Allyl Chlorides
[Image: see text] Highly enantioselective Hiyama cross-coupling reactions have been achieved through rhodium(I)-catalyzed dynamic kinetic asymmetric transformations between aryl siloxanes and cyclic racemic allyl halides. This process affords valuable enantiomerically enriched aryl-substituted cycli...
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| Published in: | Organometallics |
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| Main Authors: | , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
American Chemical Society
2019
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| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7009026/ https://ncbi.nlm.nih.gov/pubmed/32055086 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.9b00197 |
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