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Synthesis of a Smoothened Cholesterol: 18,19-Di-nor-cholesterol

[Image: see text] Herein, we report the first synthesis of a demethylated form of cholesterol (18,19-di-nor-cholesterol), in which the C18 and C19 methyl groups of the β-face were eliminated. Recent molecular simulations modeling 18,19-di-nor-cholesterol have suggested that cholesterol’s opposing ro...

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Autors principals: Mydock-McGrane, Laurel, Rath, Nigam P., Covey, Douglas F.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2014
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4076041/
https://ncbi.nlm.nih.gov/pubmed/24823889
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo500813n
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