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Competitive formation of both long-range 5´–5´ and short-range antiparallel 3´–3´ DNA interstrand cross-links by a trinuclear platinum complex on binding to a 10-mer duplex
2D [(1)H, (15)N] HSQC NMR spectroscopy has been used to monitor the reaction of fully (15)N-labelled [{trans-PtCl(NH(3))(2)}(2)(µ-trans-Pt(NH(3))(2){NH(2)(CH(2))(6)NH(2)}(2))](4+) (Triplatin, BBR3464 or 1,0,1/t,t,t ((15)N-1)) with the self-complementary 10-mer DNA duplex 5´-{d(ACGTATACGT)(2)} (duple...
Αποθηκεύτηκε σε:
| Κύριοι συγγραφείς: | , , |
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| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
2012
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4004642/ https://ncbi.nlm.nih.gov/pubmed/23165925 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2dt32079g |
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