A Confirmation of the Quench-Cryoannealing Relaxation Protocol for Identifying Reduction States of Freeze-Trapped Nitrogenase Intermediates

[Image: see text] We have advanced a mechanism for nitrogenase catalysis that rests on the identification of a low-spin EPR signal (S = 1/2) trapped during turnover of a MoFe protein as the E(4) state, which has accumulated four reducing equivalents as two [Fe–H–Fe] bridging hydrides. Because electr...

Fuld beskrivelse

Na minha lista:
Bibliografiske detaljer
Main Authors: Lukoyanov, Dmitriy, Yang, Zhi-Yong, Duval, Simon, Danyal, Karamatullah, Dean, Dennis R., Seefeldt, Lance C., Hoffman, Brian M.
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2014
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3993915/
https://ncbi.nlm.nih.gov/pubmed/24635454
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic500013c
Tags: Tilføj Tag
Ingen Tags, Vær først til at tagge denne postø!

Lignende værker