Nitrite and Hydroxylamine as Nitrogenase Substrates: Mechanistic Implications for the Pathway of N(2) Reduction

[Image: see text] Investigations of reduction of nitrite (NO(2)(–)) to ammonia (NH(3)) by nitrogenase indicate a limiting stoichiometry, NO(2)(–) + 6e(–) + 12ATP + 7H(+) → NH(3) + 2H(2)O + 12ADP + 12P(i). Two intermediates freeze-trapped during NO(2)(–) turnover by nitrogenase variants and investiga...

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Detalhes bibliográficos
Main Authors: Shaw, Sudipta, Lukoyanov, Dmitriy, Danyal, Karamatullah, Dean, Dennis R., Hoffman, Brian M., Seefeldt, Lance C.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4160268/
https://ncbi.nlm.nih.gov/pubmed/25136926
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja507123d
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