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Nitrite and Hydroxylamine as Nitrogenase Substrates: Mechanistic Implications for the Pathway of N(2) Reduction
[Image: see text] Investigations of reduction of nitrite (NO(2)(–)) to ammonia (NH(3)) by nitrogenase indicate a limiting stoichiometry, NO(2)(–) + 6e(–) + 12ATP + 7H(+) → NH(3) + 2H(2)O + 12ADP + 12P(i). Two intermediates freeze-trapped during NO(2)(–) turnover by nitrogenase variants and investiga...
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| Main Authors: | , , , , , |
|---|---|
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4160268/ https://ncbi.nlm.nih.gov/pubmed/25136926 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja507123d |
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