Diazene (HN=NH) Is a Substrate for Nitrogenase: Insights into the Pathway of N(2) Reduction

Nitrogenase catalyzes the sequential addition of six electrons and six protons to a N(2) that is bound to the active site metal cluster FeMo-cofactor, yielding two ammonia molecules. The nature of the intermediates bound to FeMo-cofactor along this reduction pathway remains unknown, although it has...

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Bibliographische Detailangaben
Hauptverfasser: Barney, Brett M., McClead, Jammi, Lukoyanov, Dmitriy, Laryukhin, Mikhail, Yang, Tran-Chin, Dean, Dennis R., Hoffman, Brian M., Seefeldt, Lance C.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2007
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2563960/
https://ncbi.nlm.nih.gov/pubmed/17508723
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi062294s
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