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Glycosyl Dithiocarbamates: β-Selective Couplings without Auxiliary Groups

[Image: see text] In this article, we evaluate glycosyl dithiocarbamates (DTCs) with unprotected C2 hydroxyls as donors in β-linked oligosaccharide synthesis. We report a mild, one-pot conversion of glycals into β-glycosyl DTCs via DMDO oxidation with subsequent ring opening by DTC salts, which can...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Padungros, Panuwat, Alberch, Laura, Wei, Alexander
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: American Chemical Society 2014
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC3985838/
https://ncbi.nlm.nih.gov/pubmed/24548247
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo500032k
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