α-Selective Glycosylation with β-Glycosyl Sulfonium Ions Prepared via Intramolecular Alkylation

[Image: see text] Stereoselective glycosylation remains the main challenge in the chemical synthesis of oligosaccharides. Herein we report a simple method to convert thioglycosides into β-sulfonium ions via an intramolecular alkylation reaction, leading to highly α-selective glycosylations for a var...

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Bibliografske podrobnosti
izdano v:J Org Chem
Main Authors: Moons, Sam J., Mensink, Rens A., Bruekers, Jeroen P. J., Vercammen, Maurits L. A., Jansen, Laura M., Boltje, Thomas J.
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2019
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6454400/
https://ncbi.nlm.nih.gov/pubmed/30808170
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b00022
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