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Stereoelectronic Effects Determine Oxa-carbenium vs β-Sulfonium Ion Mediated Glycosylations
[Image: see text] Activation of a glycosyl donor protected with a 2-O-(S)-(phenylthiomethyl)benzyl ether chiral auxiliary results in the formation of an anomeric β-sulfonium ion, which can be displaced with sugar alcohols to give corresponding α-glycosides. Sufficient deactivation of such glycosyl d...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3076600/ https://ncbi.nlm.nih.gov/pubmed/21158475 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol1027267 |
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