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Stereoselective Glycosylations of 2-Azido-2-Deoxy-Glucosides using Intermediate Sulfonium Ions
[Image: see text] TMSOTf promoted glycosylations of 2-azido-2-deoxy-glucosyl trichloroacetimidates provide excellent α-anomeric selectivities when performed at a relatively high reaction temperature in the presence of PhSEt or thiophene. NMR and computation studies have shown that these glycosylatio...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2533432/ https://ncbi.nlm.nih.gov/pubmed/17432867 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol070513b |
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