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Stereoselective Glycosylations of 2-Azido-2-Deoxy-Glucosides using Intermediate Sulfonium Ions
[Image: see text] TMSOTf promoted glycosylations of 2-azido-2-deoxy-glucosyl trichloroacetimidates provide excellent α-anomeric selectivities when performed at a relatively high reaction temperature in the presence of PhSEt or thiophene. NMR and computation studies have shown that these glycosylatio...
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| 主要な著者: | , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2007
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2533432/ https://ncbi.nlm.nih.gov/pubmed/17432867 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol070513b |
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