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Stereoselective Glycosylations of 2-Azido-2-Deoxy-Glucosides using Intermediate Sulfonium Ions

[Image: see text] TMSOTf promoted glycosylations of 2-azido-2-deoxy-glucosyl trichloroacetimidates provide excellent α-anomeric selectivities when performed at a relatively high reaction temperature in the presence of PhSEt or thiophene. NMR and computation studies have shown that these glycosylatio...

詳細記述

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書誌詳細
主要な著者: Park, Jin, Kawatkar, Sameer, Kim, Jin-Hwan, Boons, Geert-Jan
フォーマット: Artigo
言語:Inglês
出版事項: 2007
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2533432/
https://ncbi.nlm.nih.gov/pubmed/17432867
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol070513b
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