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Glycosyl Dithiocarbamates: β-Selective Couplings without Auxiliary Groups
[Image: see text] In this article, we evaluate glycosyl dithiocarbamates (DTCs) with unprotected C2 hydroxyls as donors in β-linked oligosaccharide synthesis. We report a mild, one-pot conversion of glycals into β-glycosyl DTCs via DMDO oxidation with subsequent ring opening by DTC salts, which can...
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| Autores principales: | , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3985838/ https://ncbi.nlm.nih.gov/pubmed/24548247 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo500032k |
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