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Versatile Glycosyl Sulfonates in β-Selective C-Glycosylation
C-Glycosides are both a common motif in many bioactive natural products and important glycoside mimetics. Here we demonstrate that activating a hemiacetal with a sulfonyl chloride, followed by treating the resultant glycosyl sulfonate with an enolate results in the stereospecific construction of β-l...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7054165/ https://ncbi.nlm.nih.gov/pubmed/31880395 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201914221 |
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