High Field Dynamic Nuclear Polarization NMR with Surfactant Sheltered Biradicals

[Image: see text] We illustrate the ability to place a water-insoluble biradical, bTbk, into a glycerol/water matrix with the assistance of a surfactant, sodium octyl sulfate (SOS). This surfactant approach enables a previously water insoluble biradical, bTbk, with favorable electron–electron dipola...

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Autors principals: Kiesewetter, Matthew K., Michaelis, Vladimir K., Walish, Joseph J., Griffin, Robert G., Swager, Timothy M.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2014
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3983347/
https://ncbi.nlm.nih.gov/pubmed/24506193
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp410387e
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