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Dynamic Nuclear Polarization with a Water-soluble Rigid Biradical

A new biradical polarizing agent, bTbtk-py, for dynamic nuclear polarization (DNP) experiments in aqueous media is reported. The synthesis is discussed in light of the requirements of the optimum, theoretical, biradical system. To date, the DNP NMR signal enhancement resulting from bTbtk-py is the l...

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Bibliografische gegevens
Hoofdauteurs: Kiesewetter, Matthew K., Corzilius, Björn, Smith, Albert A., Griffin, Robert G., Swager, Timothy M.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2012
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3304014/
https://ncbi.nlm.nih.gov/pubmed/22372769
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja212054e
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