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Dynamic Nuclear Polarization with a Water-soluble Rigid Biradical

A new biradical polarizing agent, bTbtk-py, for dynamic nuclear polarization (DNP) experiments in aqueous media is reported. The synthesis is discussed in light of the requirements of the optimum, theoretical, biradical system. To date, the DNP NMR signal enhancement resulting from bTbtk-py is the l...

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Main Authors: Kiesewetter, Matthew K., Corzilius, Björn, Smith, Albert A., Griffin, Robert G., Swager, Timothy M.
Formato: Artigo
Idioma:Inglês
Publicado: 2012
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3304014/
https://ncbi.nlm.nih.gov/pubmed/22372769
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja212054e
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