Rigid Orthogonal bis-TEMPO Biradicals with Improved Solubility for Dynamic Nuclear Polarization

The synthesis and characterization of oxidized bis-thioketal-trispiro dinitroxide biradicals that orient the nitroxides in a rigid, approximately orthogonal geometry is reported. The biradicals show better performance as polarizing agents in dynamic nuclear polarization (DNP) NMR experiments as comp...

Полное описание

Сохранить в:
Библиографические подробности
Главные авторы: Dane, Eric L., Corzilius, Björn, Rizzato, Egon, Stocker, Pierre, Maly, Thorsten, Smith, Albert A., Griffin, Robert G., Ouari, Olivier, Tordo, Paul, Swager, Timothy M.
Формат: Artigo
Язык:Inglês
Опубликовано: 2012
Предметы:
Article
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC3282990/
https://ncbi.nlm.nih.gov/pubmed/22304384
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo202349j
Метки: Добавить метку
Нет меток, Требуется 1-ая метка записи!

Схожие документы