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Rigid Orthogonal bis-TEMPO Biradicals with Improved Solubility for Dynamic Nuclear Polarization
The synthesis and characterization of oxidized bis-thioketal-trispiro dinitroxide biradicals that orient the nitroxides in a rigid, approximately orthogonal geometry is reported. The biradicals show better performance as polarizing agents in dynamic nuclear polarization (DNP) NMR experiments as comp...
Αποθηκεύτηκε σε:
| Κύριοι συγγραφείς: | , , , , , , , , , |
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| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
2012
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3282990/ https://ncbi.nlm.nih.gov/pubmed/22304384 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo202349j |
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