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New biphenol-based, fine-tunable monodentate phosphoramidite ligands for catalytic asymmetric transformations

Monodentate phosphoramidite ligands have been developed based on enantiopure 6,6′-dimethylbiphenols with axial chirality. These chiral ligands are easy to prepare and flexible for modifications. The fine-tuning capability of these ligands plays a significant role in achieving high enantioselectivity...

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Foilsithe in:Proc Natl Acad Sci U S A
Main Authors: Hua, Zihao, Vassar, Victor C., Choi, Hojae, Ojima, Iwao
Formáid: Artigo
Teanga:Inglês
Foilsithe: National Academy of Sciences 2004
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC397395/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/15020764/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.0307101101
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