Tunable Phosphoramidite Ligands for Asymmetric Hydrovinylation: Ligands par excellence for Generation of All-Carbon Quaternary Centers

1-Alkylstyrenes undergo efficient hydrovinylation (addition of ethylene) in the presence of a Ni-catalyst prepared from [(allyl)NiBr](2), Na(+) [BAr(4)](−) (Ar = 3,5-bis-trifluromethylphenyl), and a phosphoramidite ligand giving products in excellent yields and enantioselectivities. In many cases ph...

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Bibliographic Details
Main Authors: Smith, Craig R., Lim, Hwan Jung, Zhang, Aibin, RajanBabu, T. V.
Format: Artigo
Language:Inglês
Published: 2009
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2745151/
https://ncbi.nlm.nih.gov/pubmed/19763244
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0029-1216826
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