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Ethylene in Organic Synthesis. A New Route to Anticholenergic Pyrrolidinoindolines, and Other Molecules with All Carbon-Quaternary Centers via Asymmetric Hydrovinylation
[Image: see text] The asymmetric hydrovinylation (1 mol % Ni-cat., 1 atm, ethylene, >98% ee) products from 1-methylenetetralines are readily converted into 3,3-disubstituted oxindoles, and subsequently to pyrrolidinoindolines. These hydrovinylation products are also useful for the syntheses of en...
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| Главные авторы: | , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2011
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3237796/ https://ncbi.nlm.nih.gov/pubmed/22103775 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol203052y |
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