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Ethylene in Organic Synthesis. A New Route to Anticholenergic Pyrrolidinoindolines, and Other Molecules with All Carbon-Quaternary Centers via Asymmetric Hydrovinylation

[Image: see text] The asymmetric hydrovinylation (1 mol % Ni-cat., 1 atm, ethylene, >98% ee) products from 1-methylenetetralines are readily converted into 3,3-disubstituted oxindoles, and subsequently to pyrrolidinoindolines. These hydrovinylation products are also useful for the syntheses of en...

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Détails bibliographiques
Auteurs principaux: Lim, Hwan Jung, RajanBabu, T. V.
Format: Artigo
Langue:Inglês
Publié: 2011
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3237796/
https://ncbi.nlm.nih.gov/pubmed/22103775
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol203052y
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