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Asymmetric Hydrovinylation of Vinylindoles. A Facile Route to Cyclo-penta[g]indole Natural Products (+)-cis-Trikentrin A and (+)-cis-Trikentrin B

Vinylindoles undergo Ni(II)-catalyzed asymmetric hydrovinylation under very mild conditions (−78 °C, 1 atmosphere ethylene, 4 mol% catalyst) to give the corresponding 2-but-3-enyl derivatives in excellent yields and enantiose-lectivities. Hydroboration of the alkene, oxidation to an acid, followed b...

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Hlavní autoři: Liu, Wang, Lim, Hwan Jung, RajanBabu, T. V.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3315614/
https://ncbi.nlm.nih.gov/pubmed/22394308
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3004733
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