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Asymmetric Hydrovinylation of Vinylindoles. A Facile Route to Cyclo-penta[g]indole Natural Products (+)-cis-Trikentrin A and (+)-cis-Trikentrin B
Vinylindoles undergo Ni(II)-catalyzed asymmetric hydrovinylation under very mild conditions (−78 °C, 1 atmosphere ethylene, 4 mol% catalyst) to give the corresponding 2-but-3-enyl derivatives in excellent yields and enantiose-lectivities. Hydroboration of the alkene, oxidation to an acid, followed b...
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| Huvudupphovsmän: | , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2012
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3315614/ https://ncbi.nlm.nih.gov/pubmed/22394308 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3004733 |
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